Study of the Reactions of Fullerene С&lt;inf&gt;60&lt;/inf&gt; with the Palladium-Containing Clusters of Molybdenum {Mo&lt;inf&gt;3&lt;/inf&gt;PdS&lt;inf&gt;4&lt;/inf&gt;} by Spectroscopic and Calculation Methods

Laricheva Y.A.; Shmelev N.Y.; Gushchin A.L.; Sokolov M.N.

Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods

Laricheva Y.A., Shmelev N.Y., Gushchin A.L., Sokolov M.N.

Дата публикации: 2021

Дата публикации в реестре: 2022-10-06T16:04:26Z

Аннотация:

Abstract: The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.

Ключевые слова:
cluster complexes, DFT calculations, fullerene, molybdenum, palladium

Тип: Article

Источник: SCOPUS10703284-2021-47-3-SID85102953196