MOFs (Metal-Organic Frameworks) materials MOF-5 (Zn4O(1,4-benzenedicarboxylate)3 и MOF-177 (Zn4O(4,4',4''-benzene-1,3,5-triyltribenzoate) were synthesized by different methods such as electrochemical, solvothermal, microwave-assisted. Physical-chemical properties of the MOFs (crystal structure, thermal stability) were investigated.