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Rationalization of the mechanism and chemoselectivity of versatile Au-catalyzed reactions of diazoesters with allyl-functionalized sulfides, selenides, amines, or ethers by DFT free ylide intermediate. With an allyl amine as the second reactant, the main pathway is a selective

Amine adducts of triallylborane as highly reactive allylborating agents for Cu(i)-catalyzed allylation of chiral sulfinyliminesConvenient, atom-efficient allylation reagents with high selectivity and tunable reactivity

Application of New Efficient Hoveyda-Grubbs Catalysts Comprising an N→Ru Coordinate Bond in a Six-Membered Ring for the Synthesis of Natural Product-Like Cyclopenta[b]furo[2,3-c]pyrrolesThe ring rearrangement metathesis (RRM) of a trans-cis diastereomer mixture of methyl 3-allyl-3a,6

The short route to chalcogenurea-substituted 3a,6-epoxyisoindoles via an intramolecular Diels-Alder furan (IMDAF) reaction. Antibacterial and antifungal activityAllyl amine

Application of the intramolecular Diels-Alder vinylarene (IMDAV) reaction for the synthesis of benzo-, carbocyclo-, thienothiopheneisoindolecarboxylic acids and its limitationsAllyl amine

An intramolecular Diels–Alder reaction in the synthesis of N-aroyl-3a,6-epoxyisoindole-2-carbothioamides(Figure presented.) The reaction of allyl(furfuryl)amines with aroyl isothiocyanates was studied

Synthesis of 2-furilpergidroaza heterocycles and their transformation under the influence of anhydrides unsaturated's acids if the furan fragment is in the α-position. We synthesized cyclic α-furilsubstituted amines, and the example

Not all carbon—carbon bonds are equivalent: anomeric effect of sp-hybridized carbon atom, which can affect the reactivity of acetylenes. For the N-benzyl systems (9.4 kcal mol−1) and N-allyl (9

Imino [4+4] cycloaddition products as exclusive and biologically relevant acrolein-amine conjugates are intermediates of 3-formyl-3,4-dehydropiperidine (FDP), an acrolein biomarker of the reaction, through an imino [4+4] cycloaddition, of biologically relevant amines with acrolein

Synthesis of epoxyisoindolo[1,2-a]isoquinolinium salts by an intramolecular [2+4] cycloaddition reaction in 2-allyl-1-furylisoquinolinium halides by various allyl halides. It was found that the process occurred through the intermediate formation of 2

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