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Transition Metal-Catalyzed Intermolecular Cascade C−H Activation/Annulation Processes for the Synthesis of Polycycles for the fields of organic/medicinal/materials chemistry. Among them, transition metal-catalyzed C−H activation

Intramolecular cascade annulation triggered by rhodium(III)catalyzed sequential C(sp 2 )–H activation and C(sp 3 )–H amination-hydroxyacrylamides for the construction of indolizinones via sequential C(sp 2 )–H activation and C(sp 3 )–H amination has been developed

Transition Metal-Catalyzed C−H Activation/Annulation Approaches to Isoindolo[2,1-b]isoquinolin-5(7H)-ones metal-catalyzed C−H activation/annulation is emerging as a powerful and straightforward method

Direct C-2 acylation of indoles with toluene derivatives via Pd(II)-catalyzed C-H activationA simple and efficient Pd-catalyzed method for the C2-acylation of indoles is described. Less toxic

Ligand-Enabled Palladium-Catalyzed Through-Space C−H Bond Activation via a Carbopalladation/1,4-Pd Migration/C−H Functionalization Sequence-migration and C(sp2)−C(sp2) bond formation to construct a variety of bis-heterocyclic frameworks in a single

Recent Developments in Transition-Metal Catalyzed Direct C-H Alkenylation, Alkylation, and Alkynylation of AzolesThe transition metal-catalyzed C-H bond functionalization of azoles has emerged as one of the most

Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center in the generation of a labile monomeric oxide, NacNacGa(O), which can easily cleave the C−H bonds of aliphatic

Metal-organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C-H bond activation and functionalization reactions active and selective catalysts. Recently, C-H-active transformations using porous materials

Ruthenium-catalyzed cascade C-H activation/annulation of: N -alkoxybenzamides: Reaction development and mechanistic insightA highly selective ruthenium-catalyzed C-H activation/annulation of alkyne-tethered N

Intramolecular cascade annulation triggered by C–H activation via rhodium hydride intermediate of indolizinones triggered by rhodium(III)-catalyzed sequential C(sp2)-H activation and C(sp3)-H amination

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