Intramolecular cascade annulation triggered by rhodium(III)catalyzed sequential C(sp 2 )–H activation and C(sp 3 )–H amination-hydroxyacrylamides for the construction of indolizinones via sequential
C(sp 2 )–
H activation and
C(sp 3 )–
H amination has been developed
Direct C-2 acylation of indoles with toluene derivatives via Pd(II)-catalyzed C-H activationA simple and efficient Pd-catalyzed method for the
C2-acylation of indoles is described. Less toxic
Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center in the generation of a labile monomeric oxide, NacNacGa(O), which can easily cleave the
C−H bonds of aliphatic
Intramolecular cascade annulation triggered by C–H activation via rhodium hydride intermediate of indolizinones triggered by rhodium(III)-catalyzed sequential
C(sp2)-
H activation and
C(sp3)-
H amination