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Nickel and palladium N-heterocyclic carbene complexes. Synthesis and application in cross-coupling reactions (NHCs) are widely used as ligands in catalysis by transition metal complexes. The catalytic activity

An octahedral cobalt(iii) complex based on cheap 1,2-phenylenediamine as a bifunctional metal-templated hydrogen bond donor catalyst for fixation of CO2with epoxides under ambient conditions for the activation of compounds in synthetic chemistry. Among them, the metal-templated HBD complexes present

Role of metal center and coordination environment in M-(Z)-N-((E)-pyridin-2-ylmethylene)isonicotinohydrazonate (M = LaIII, ZnII, CdII or HgII) catalyzed cyanosilylation of aldehydesA series of known metal complexes, [LaL2(NO3)(H2O)2]·5H2O (1), [Zn(μ-L)(NO3)(H2O)]n (2), {[Cd2(μ

Xenon Derivatives as Aerogen Bond-Donating Catalysts for Organic Transformations: A Theoretical Study on the Metaphorical “Spherical Cow in a Vacuum” Provides Insights into Noncovalent Organocatalysis in a strong negative correlation between the calculated Gibbs free energies of activation

A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki-Heck Reaction of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal

Novel organotin-PTA complexes supported on mesoporous carbon materials as recyclable catalysts for solvent-free cyanosilylation of aldehydes and under microwave irradiation in solvent-free conditions. Multinuclear NMR analysis suggested a mechanism

Polyaromatic Group Embedded Cd(II)-Coordination Polymers for Microwave-Assisted Solvent-Free Strecker-Type Cyanation of Acetals-assisted solvent-free Strecker-type cyanation of different acetals. Solvothermal reaction between the pro-ligand, 5

Isothiazoles in the Design and Synthesis of Biologically Active Substances and Ligands for Metal Complexes of existing literature in the field of metal complexes of isothiazoles is given, including the results

Recent developments in metal/metalloid nanomaterials for battery applications; a comparative review of nanotechnology in batteries, particularly with a study of metal/metalloid-based nanoparticles due to their superb

Metal-free and iron(II)-assisted oxidation of cyclohexane to adipic acid with ozone: A theoretical mechanistic studyH) oxidation with ozone into adipic acid under room temperature and radiation-free conditions, both metal-free

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