A mechanistic study of the Lewis acid-Brønsted base-Brønsted acid catalysed asymmetric Michael addition of diethyl malonate to cyclohexenoneSamoilichenko Y.,
Kondratenko V.,
Ezernitskaya M.,
Lyssenko K.,
Peregudov A.,
Khrustalev V.,
Maleev V.,
Moskalenko M.,
North M.,
Tsaloev A.,
Gugkaeva Z.T.,
Belokon Y. The
Michael addition of diethyl malonate (
Michael Donor, MD) to cyclohexenone (
Michael Acceptor, MA
Expert system for predicting reaction conditions: The Michael reaction case synthetic protocols may be successful. For example,
Michael β-addition reactions may proceed under different
Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bondHayriyan L.A.,
Mkrtchyan A.F.,
Moskalenko M.A.,
Maleev V.I.,
Gugkaeva Z.T.,
Ilyin M.M.,
Babievsky K.K.,
Dorovatovskii P.V.,
Khrustalev V.N.,
Peregudov A.S.,
Belokon Y.N. with carboxylic anhydrides and di-tert-butyl acetylenedicarboxylate. An unusual
Michael addition intermediate